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Khoo, Iam Choon (Ed.)Lenses with tunable focal lengths play important roles in nature as well as modern technologies. In recent years, the demand for electrically tunable lenses and lens arrays has grown, driven by the increasing interest in augmented and virtual reality, as well as sensing applications. In this paper, we present a novel type of electrically tunable microlens utilizing polymer-stabilized chiral ferroelectric nematic liquid crystal. The lens offers a fast response time (5ms) and the focal length can be tuned by applying an in-plane electric field. The electrically induced change in the lens shape, facilitated by the remarkable sensitivity of the chiral ferroelectric nematic to electric fields, enables the tunable focal length capability. The achieved performance of this lens represents a significant advancement compared to electrowetting-based liquid lenses and opens exciting prospects in various fields, including biomimetic optics, security printing, solar energy concentration, and AR/VR devices.more » « less
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A unique morphology for bent-core liquid crystals forming the B4 phase has been found for a class of tris-biphenyl bent-core liquid crystal molecules with a single chiral side chain in the longer para -side of the molecule. Unlike the parent molecules with two chiral side chains or a chiral side chain in the shorter meta -side, which form helical nano- or microfilament B4 phases, the two derivatives described here form heliconical-layered nanocylinders composed of up to 10 coaxial heliconical layers, which can split or merge, braid, and self-assemble into a variety of modes including feather- or herringbone-type structures, concentric rings, or hollow nest-like superstructures. These multi-level hierarchical self-assembled structures, rivaling muscle fibers, display blue structural color and show immense structural and morphological complexity.more » « less
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Abstract The range of possible morphologies for bent‐core B4 phase liquid crystals has recently expanded from helical nanofilaments (HNFs) and modulated HNFs to dual modulated HNFs, helical microfilaments, and heliconical‐layered nanocylinders. These new morphologies are observed when one or both aliphatic side chains contain a chiral center. Here, the following questions are addressed: which of these two chiral centers controls the handedness (helicity) and which morphology of the nanofilaments is formed by bent‐core liquid crystals with tris‐biphenyl diester core flanked by two chiral 2‐octyloxy side chains? The combined results reveal that the longer arm of these nonsymmetric bent‐core liquid crystals controls the handedness of the resulting dual modulated HNFs. These derivatives with opposite configuration of the two chiral side chains now feature twice as large dimensions compared to the homochiral derivatives with identical configuration. These results are supported by density functional theory calculations and stochastic dynamic atomistic simulations, which reveal that the relative difference between thepara‐ andmeta‐sides of the described series of compounds drives the variation in morphology. Finally, X‐ray diffraction, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM) data also uncover the new morphology for B4 phases featuringp2/msymmetry within the filaments and less pronounced crystalline character.more » « less
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